Micro thruster, micro thruster array and polymer gas generator

ABSTRACT

Disclosed is a gas generating polymer compound that when irradiated with light or other radiation sources makes a solid to gas phase transition due to chemically catylized degradation, irradiative degradation or both. This provides a low cost, stable and easily manufactured means of gas production. Also disclosed are possible uses for the gas generator such as a low cost micro thruster.

CROSS REFERENCE TO RELATED APPLICATION

This application claims priority under 35 U.S.C. 119 from ProvisionalPatent Application Ser. Nos. 60/621,015 filed Oct. 20, 2004 and60/698,501, filed Jul. 11, 2005, which are incorporated by reference.

FIELD OF THE INVENTION

The present invention relates to micro thrusters, micro thruster arraysand polymer gas generators that are photo reactive or initiated andsystems for their use.

DESCRIPTION OF PRIOR ART

Micro thrusters and micro thruster arrays typically are fabricatedexpensive using semi conductor materials. Such devices are difficult andexpensive to manufacture. U.S. Pat. No. 6,378,292 to Youngner, issuedApr. 30, 2002, describes a microelectrical mechanical system (MEMS)micro thruster array. The MEMS micro thruster array described can beused for maintaining inter satellite distance in small satellites. Onemicro thruster array includes numerous micro thruster propulsion cells,each having a vacuum enclosed explosive igniter disposed on one side bya breakable diaphragm and having a propellant-filled chamber on theopposite side of the diaphragm. Upon explosion of the explosive igniter,the first diaphragm breaks, which, together with the explosion of theexplosive igniter, causes the propellant to expand rapidly, therebyproviding exhaust gases which are ejected from an exterior face of themicro thruster propulsion array, thereby providing a small unit ofthrust.

SUMMARY OF THE INVENTION

The present invention provides improvements over existing microthrusters and micro thruster arrays. More particularly, the presentinvention provides micro thruster and micro thruster arrays formed asone or an array of stable polymer gel gas generator cells molded orformed with the surrounding housing and then covered with a protectiveouter shell. The cells are activated by UV or other light wave lengthirradiation introduced, for example, at the back or other point of eachcell via fiber optics. This design simplifies manufacturing andassembly, and achieves a substantial cost and weight reduction of thepackage by using compatible polymer materials. Using compatiblematerials eliminates the problems associated with bonding layers ofdissimilar materials used in MEMS and other micro thruster fabrication.This design also eliminates assembly and storage problems associatedwith many propellants for further cost savings.

One configuration of the system uses UV photo acid generators that aresuspended in polymer gel base material containing additional chemicalsnecessary to create a robust gas reaction when the photo acid ispresent. In turn this reaction produces a highly energetic and reactivegas. This gas can be used for thrust two ways: cold or with the additionof igniters hot for increased performance.

BRIEF DESCRIPTION OF THE DRAWINGS

Other features and advantages of the present invention will be seen fromthe following detailed description, taken in conjunction with theaccompanying drawings, wherein:

FIG. 1 is a cross-sectional view of a micro thruster; and

FIG. 2 is a partially exploded perspective view of a micro thrusterarray made in accordance with a preferred embodiment of the presentinvention.

DETAILED DESCRIPTION FOR THE PREFERRED EMBODIMENTS

Gas generators are used for many functions but primarily as auto air baginflators. These need a means of ignition and are basically controlledexplosions that go through a catalytic chemical process. See, U.S. Pat.No. 6,864,295 to Mitarai issued Mar. 8, 2005, which describes agas-generating, pressure-sensitive adhesive composition comprising apressure-sensitive, ultraviolet irradiation-curable adhesive containinga photoinitiator, wherein the adhesive allows through ultravioletradiation, and a gas generator compound which generates a gas uponirradiation with an ultraviolet radiation, the gas generator compoundgenerates a gas and the gas effuses at an interface between thegas-generating, pressure-sensitive adhesive composition to therebyfacilitate release of the pressure-sensitive adhesive composition.

Referring to FIG. 1, a micro thruster cell 10 made in accordance withthe present invention comprises a base 16 with a well 11 with embeddedfiber optics 12. A reactive polymer 14 is contained in well 11, andcovered with a protective cover or shell 18 having an orifice orweakened area 19.

Referring also to FIG. 2, a plurality of cells 10 may be assembled,suspended or confined within a polymer gel base 17.

Once the body and cells are formed the outer shell cover material couldbe applied so that the cell cover can burst, at a predeterminedpressure, at points over each gas generator. Possible shell coatingmaterials are ceramic polymer compositions, polymer composites, polymermetal composites.

Various gas generating polymers are available commercially andadvantageously can be used in accordance with the present invention.Generally, the gas generating polymer composition comprises a photo acidgenerator (A) and a polymer (B) that has a chain or branches susceptibleto acidylic attack and converts to gas when the chain is cleaved by acidformed from photo irradiation of said photo acid generator (A).Preferred are photo acid generators (PAG) such as Trisulfonium acid andother photo acid generators commercially available from chemicalcompanies such as CIGMA Aldrich of Milwaukee, Wis. In a preferredembodiment of the invention, the photo acid generators may be chemicallyamplified using photo initiators.

In a particularly preferred embodiment the polymer, Acetal resin orPolyoxymethylene is mixed with photo acid generators or its chain endcapped with photo initiators. The polymer readily decomposes to the gasformaldehyde both in the presence of acids and UV radiation. Acetalresin is also attractive for its ability to be engineered andcopolymerized. This allows the reaction gas or products to be engineeredto produce a highly energetic and reactive gas. This gas can be used forthrust two ways cold or with the addition of igniters or combustionchamber hot for increased performance. The scope of the invention is notmeant to be limited to the use of Acetal resins as the polymercompounds, for there are an abundance of highly engineered polymers andcopolymers available.

Acetal resin is cryogenically pulverized to micron sized powder andmixed with the photo acid per the process needed for the PAG; thisprocess is material specific and would be obvious to anyone in the art.The PAG is then put into the thruster cavity or body. It can also be putinto molds and cured into a solid or gel. The micro thruster consist ofa body or cavity that is machined, molded or assembled using a polymeror polymer ceramic hybrid material that is not susceptible to acid orphoto degradation.

Within the body or cavity are means for light transmission such as fiberoptics that channel the photo energy to the PAG and polymer mixture.Acetal resin degrades in a boundary layer when the acid and light arepresent so the mixture can be illuminated from the center axis out byusing a side illuminating fiber optic strand, by embedding an LED, orlaser chip into the micro thruster cavity.

Once the body and gas generating material are assembled they can becapped with compatible material such as a ceramic polymer slurry thatcan be poured sprayed or cast to the body, cured thus sealing in the gasgenerating material. This may be sufficient protection and encapsulationor a protective outer layer may need to be applied depending on theenvironment the thruster needs to work in this outer layer may consistof metal thin film, ceramic polymer, composites etc. the outer shellcoating material would be applied so that the sell can burst, at apredetermined pressure, at points over each gas generator. Electrodes origniters may also need to be added also dependant on the workingenvironment and performance requirements. The micro thruster or array isthen attached to a power and control source and added to the system itis designed for.

The system includes a controller such as a microprocessor controller 26which controls via electronic/photonic switching one or more UV lightsources 22. These can be in the form of LEDs for the lowest cost oflaser chips to ensure system reliability. By applying simple chemistryit is possible to build a low cost controllable and consumable on demandgas generation system activated with low power (<2 v) UV irradiation.

Operation of the micro thruster array is quite straight forward. Whenone turns on the UV light source the reactive polymer produces gas; turnoff the light source and the gas generation stops. This reactive polymercan be consumable or non-consumable and easily manufactured. Theassembly of components can be accomplished via molding or cutting thepolymer base and polymer gas generators to shape, and then depositing orcoating the shell material to complete micro thruster array. The designlends itself to high production principals with very few steps ofassembly and can be made in sheet or strip forms. Moreover, the systemsarray can be integrated directly into other interceptor parts reducingassembly, cost and weight even further.

In summary the invention provides a gas generating system that when theirradiative source is activated the gas generating material producesgas, turn it off and the gas generation stops. This material can beconsumable or non consumable and easily manufactured. The assembly ofcomponents can be accomplished via molding or cutting the materials toshape and then depositing or coating the shell material over thecomplete micro thruster array, lamination of sheets of material isanother option for this process. The design lends itself to highproduction principals with very few steps of assembly and can be made insheet or strip forms.

There are many variations of the invention possible and this descriptionis not meant to limit the scope of the invention or its variables suchas polymer compositions, types of gas generated, light wavelength andpower and source, controller and main power source.

1-29. (canceled)
 30. A micro thruster comprising a gas generatingpropellant, wherein the gas generating propellant comprises a gasgenerating polymer composition comprising: a photo acid generator (A),and a polymer (B) that has a chain or branches susceptible to acidylicattack and converts to a gas when the chain is cleaved by acid formedfrom photo irradiation of the photo acid generator (A).
 31. The microthruster according to claim 30, wherein the polymer (B) is subject tophoto degradation and converts to a gas under photo irradiation.
 32. Themicro thruster according to claim 30, wherein the gas generating polymercomposition further comprises a polymer (C) that is subject to photodegradation and converts to a gas under photo irradiation.
 33. The microthruster according to claim 30, wherein the gas generating polymercomposition further comprises a photo initiator.